Taxi - at the curb - there's a disciplined taxi line at the left hand exit of the station, immediately to the right. Viale Don Minzoni is really not central. The ride will probably be around 10/15 euros.
Viale Don Minzoni is a wide, busy, nasty thoroughfare about one and a quarter miles from the railroad station.
Take a taxi.
You didn't ask this question, but I would recommend you think about staying somewhere else.
There are hundreds of reasonably priced hotels in much better locations in Florence.
Florence is a tiny city designed for walking. The Meridiana is just too far a way to make that convenient, and it's in an unpleasant commercial neighborhood with nothing of any interest.
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