This is primarily a review recommending a visit to the Pululahua Geobotanical Reserve, but while you're there, I recommend staying at the Pululahua Hostal, described at greater length by other reviewers, and mentioned briefly at the end of this review.
The first surface I'm referring to is the volcano as seen from the rim, which is gorgeous in itself. I tend to be curious when I'm traveling, and I was curious to see what this botanical reserve was all about. I first saw it from the Hotel El Crater at the Mirador above the volcano. Then I drove to the road leading to the park entrance a few kilometers farther west (Moraspungo sector, near Calacali). I was driving a Chevy Spark, not the sort of vehicle most people would normally consider for rough-road driving; but I'm writing this review partly to encourage anyone with similar curiosity not to be put off by the already-evident challenge of just getting to the park entrance at the top of the volcano. In short, I had not made any reservations and didn't really know what to expect.
The second surface to look beneath is what you can see from the road leading down the inside of the volcano, not because the vistas are not equally gorgeous as that from the top, but because another dimension of natural beauty is not available until you finally reach the trails in the caldera on foot (or horseback). In short, again, the payoff is worth the effort.
And I agree with all the comments made about Pululahua Hostal, which I believe is also the only place available just about every day year-round. On this trip I had a loose itinerary which constrained me from enjoying more than one of the shorter trails the afternoon of my arrival. When I go back, I plan to spend more time there and, at least, rent a GPS to get me to, and back from, some of the trails farther from the hostal.
This review is the subjective opinion of a TripAdvisor member and not of TripAdvisor LLC