Large hotel in excellent location - particularly for a quick stay. The bus from the train station is a block away as well as the main square with the information center.
Great buffet breakfast, very nice staff and comfortable bed.
Only drawback was the 12 euro fee per day for wifi access and perhaps not in the center of the action - if you are looking for that. But probably quieter as a result.

We had 2 rooms adjoining across a lovely patio with a view of the beautiful roofs of Toledo. We, the parents, had a room with a bathroom that had a smell coming from a floor drain that was almost nauseating. Had it not been for the view, we would have moved hotels. The patio was so lovely we got a picnic lunch one day and ate up there. We had to pay for internet service which was the first and only time in Spain we did not find it for free. The guests in the next room came in late one night and it sounded like their TV was right in our room. Very unsettling. In other cities I had booked hotels thru Inns of Spain and found the hotels to be absolutely lovely, quiet, minibars in every room, big towels, free internet service, very helpful staff. Also, at Alfonso, they required us to eat the hotel breakfast which we had not been doing at other hotels nor did we want to have such a big breakfast for quite an expense. We found the experience not up to what our other experiences had been in Spain and the price was about the same at the other hotels.

what can I say, staff were clearly tired, as was the hotel, however the room was very nice, with a great view over the town, we slept well, but arrriving at breakfast at 9o/c it looked like a plague of locusts had beaten us to it. I would not stay there again.

By the time we arrived in Toledo we had been robbed twice(once in the Barcelona train station, and again on the Madrid metro-lambs to the slaughter!). Then, the second day in Toledo I twisted my ankle. The Alfonso VI was the perfect place to lick our wounds. We were determined not to allow our trip to be spoiled, and were very glad to have such a comfortable room to rest and regroup in. We had a wonderful view from our balcony and were able to gather strength and energy to enjoy the rest of our vacation. It is true that the staff was kind of grumpy, but they were also elegant and sort of old fashoned. It was like a hotel from another time-very relaxing and easy to be in. I am only sorry that the room was painted a sort of toothpaste green-who knows why these things happen.